6. Heterogeneous Catalysis and Related Model Systems

1. A. Müller, E. Diemann
   "[Mo₃^IVS₁₃]^2-, a Model for Crystalline MoS₂: Remarks on the Thermal Decomposition of (NH₄)₂[Mo₃S₁₃] .n H₂O and its Catalytical Relevance"
   Chimia 39, 312-313 (1985)
   
   
2. A. Müller, E. Krickemeyer, R. Jostes, H. Bögge, E. Diemann, U. Bergmann
   "Über [Co₄S₃(SO)(CN)₁₂]^8-: bemerkenswerte Bildung eines Clusters und eines "SO"-Liganden sowie Relevanz zum Promotor-Effekt bei der HDS-Katalyse"
   Z. Naturforsch. 40b, 1715-1718 (1985)
   
   
3. H. Topsoe, B. S. Clausen, N.-Y. Topsoe, E. Pedersen, W. Niemann, A. Müller, H. Bögge, B. Lengeler
   "Inorganic Cluster Compounds as Models for the Structure of Active Sites in Promoted Hydrodesulphurization Catalysts"
   J. Chem. Soc., Faraday Trans. I. 83, 2157-2167 (1987)
   
   
4. W. Eltzner, M. Breysse, M. Lacroix, C. Leclercq, M. Vrinat, A. Müller, E. Diemann
   "A New Highly Active Hydrotreating Catalyst Prepared by the Decomposition of Thiotungstatonickelate and Characterized by High Resolution Electron Microscopy"
   Polyhedron 7, 2405-2409 (1988)
   
   
5. A. Müller, E. Diemann, F. W. Baumann
   "Hydrodesulfurierung, Katalysatoren für die Erdöl-Entschwefelung"
   Nachr. Chem. Tech. Lab. 36, 18 (1988)
   
   
6. A. Müller, E. Diemann, A. Branding, F. W. Baumann, M. Breysse, M. Vrinat
   "A New Method for the Preparation of Hydrodesulfurization Catalysts: Use of the Molybdenum Sulphur Cluster Compound (NH₄)₂[Mo₃^IVS₁₃]"
   Appl. Catal. 62, L13-L17 (1990)
   
   
7. A. Müller, T. Weber
   "In situ Raman investigation of hydrodesulphurization catalysts"
   Appl. Catal. 77, 243-250 (1991)
   
   
8. E. Diemann, A. Branding, A. Müller
   "A Scanning Tunneling Microscopial (STM) Study of (NH₄)₂[Mo₃S₁₃].H₂O and its Thermal Decomposition Product MoS₂"
   Bull. Soc. Chim. Belg. 100, 961-966 (1991)
   
   
9. A. Müller, E. Krickemeyer, H. Bögge, D. Rehder
   "Discrimination between S^2- and SO^2- Sites in Mixed Crystal Compounds Containing Co and Co/Mo Clusters by ⁵⁹Co-NMR Spectroscopy, and the Relevance for HDS Catalysis"
   Chimia 46, 386-388 (1992)
   
   
10. P. Mottner, A. Lerf, T. Butz, H. Knözinger, A. Müller, V. Wittneben, E. Krickemeyer
    "Nuclear quadrupole interaction of ⁹⁹Mo(b^-)⁹⁹Tc in various molybdenum sulfur cluster compounds and thermal decomposition products of (NH₄)₂[Mo₃S(S₂)₆].nH₂O(n=0-2)"
    Chem. Phys. 160, 327-339 (1992)
    
    
11. E. Diemann, Th. Weber, A. Müller
    "Modeling the Thiophene HDS Reaction on a Molecular Level"
    J. Catal. 148, 288-303 (1994)